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GLAZED HARD PORCELAIN TITANIUM OXIDE ALUMINIUM OXIDE ALUMINA - ZIRCONIA
ZIRCONIUM OXIDE SILICON CARBIDE SILICON NITRIDE PRODUCTION PROCESSES
  ZIRCONIUM OXIDE
The product Zirconium oxide is obtained by chemical or electro-fusion processes from natural products such as zirconium silicate and baddeleyte. Pure zirconium oxide is useless as a ceramic because it undergoes a phase change as it passes through temperatures around 1000°C. The resulting change in volume disrupts any sintered article. It is then stabilised with MgO or Y2O3.
 
Properties Zirconium oxide stabilised with yttrium (ZrO2Y-PSZ): excellent toughness; high bending strength; excellent cutting qualities, low friction coefficient.
Zirconium oxide stabilised with magnesium (ZrO2Mg-PSZ): good wear resistance, low friction coefficient, good thermal shock resistance, low thermal expansion, good toughness and very low thermal conductivity (one of the lowest among ceramic materials).
 
Applications Thread guides with mechanical stresses; mechanical components particulary wear resistant; the material BZ-1 has a good “flexibility” and is particularly suitable for scissors blades, for thread cutters, for selvedges-cutters, etc.
 
    Production processes   Dry and isostatic pressing; injection moulding.  
 
Technical data The following table gives physical and mechanical data. Material data are obtained from specimens according to international test specifications. The indicated values can’t be extended to components and parts with different shapes and surface finishings.
Bettini S.r.l. reserves the right to make technical modifications.

BETTINI CERAMICS STABILIZED ZIRCONIUM OXIDE
WITH YTTRIUM OXIDE WITH MAGNESIUM OXIDE
MATERIAL CODE   BZ-1 BZ-2
COLOUR   White Black Yellow
SPECIFIC WEIGHT g/cm3 6,00 5,85 5,65
H20 ABSORPTION % 0 0 0
VICKERS HARDNESS (HV, 500g) GPa 13,0 12,5 12,0
COMPRESSIVE STRENGTH MPa 2800 2500 2500
FLEXURAL STRENGTH MPa 1000 800 450
YOUNG'S MODULUS (E) GPa 200 190 200
FRACTURE TOUGHNESS (Kic) MPa m1/2 10 NA 7
MAX. SERVICE TEMPERATURE °C 1000 800 1000
THERMAL CONDUCTIVITY W / m K 2 2 2
THERMAL EXPANSION COEFFICIENT 20°C - 400°C x 10-6 / °C 9,6 9,9 9,7
20°C - 800°C x 10-6 / °C 10,7 10,3 11,0
 
Dimensional tolerances Standard tolerances: up to 10mm: ± 0.2mm, above 10mm: ± 2%
Bending deformation: max. 0.5% of part length
Very close tolerances can be reached by grinding and polishing sintered parts, normally up to quality class IT8. Few microns tolerances can be achieved if needed.
NEAR-NET SHAPE can be obtained by injection moulding reducing hard machining operations.
 
Surface finishings The sintered products are manufactured with the following surface finishings

Ground Ra from 0,6 to 1,6 µm;
Satin Ra ≤ 0,8 µm;
Polished satin Ra up to 0,4 µm;
Diamond-polished Ra ≤ 0,2 µm.
 
Some examples of microstructure
Polished of magnesia-stabilised zirconia with the typical “tiled” structure,
magnified 250X,
SEM micrograph.
Ra 0.0467 µm
Roughness metre:
Gauss cut off 7*0.8mm,
diamond tip cone 60° 2 micron


The examples reported are indicative only. For further information please contact our
technical staff.
 
Friction coefficient Friction coefficient diagram for material with Ra ≤ 0,4 µm


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